For type 316 austenitic stainless steel, a slope of 91 mv was reported for cl. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and incurs plant downtime. Stress corrosion cracking scc of austenitic stainless steel weld metal. Higher nickel austenitic steels have increased resistance to stress corrosion cracking. The phenomenon of transgranular stress corrosion cracking of austenitic stainless steels in aqueous chloride environments has been recognized. Stress corrosion cracking scc of austenitic stainless.
In this study, ground steel surfaces were subjected to a series of sand blasting and wire brushing. In this paper, the effect of 1 wt%ru additions on the scc susceptibility of 304. Addition of nitrite to the chloride solution, which is reported to have inhibitive influence on corrosion of stainless. Chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. Stress corrosion cracking of austenitic stainless steels. The mechanism of scc is shown as a simple representation in figure 1. The scc propensity of austenitic stainless steels in marine environments is affected by many variables including the amount of moisture and time of wetness, airborne contaminants e. Stress corrosion cracking scc is the formation and growth of crack through. Stress corrosion cracking is a general term describing stressed alloy failures appearing as cracks in the stainless steel that occur in corrosive environments.
The stress corrosion cracking of austenitic stainless steel heat exchange tubes. Surface finishing treatments such as shot blasting and wire brushing can be beneficial in improving the integrity of machined surfaces of austenitic stainless steels. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Behaviour of stress corrosion cracking of austenitic. Stress corrosion cracking behavior of alloys in aggressive. Chloride induced stress corrosion cracking ciscc is a significant problem. Stress corrosion cracking scc is one failure mode that may occurred on hot insulated austenitic stainless steel pressure vessels and piping. When bare steel is subjected to water on a regular basis, it rusts. Stress corrosion cracking scc of austenitic stainless steels has been a. We use cookies on our website to ensure you get the best experience.
Stress corrosion cracking of an austenitic stainless steel. They are nominally nonmagnetic but usually exhibit some magnetic response depending on the composition and the work hardening of the steel. Localized corrosion and stress corrosion cracking of stainless steels. Chlorideoxygen stress corrosion cracking mechanisms of austenitic chromiumnickel steels in high purity water at 250 to 350 c over a wide range of stress levels is reported.
Stress corrosion cracking of an austenitic stainless steel in. The study was to define conditions to prevent igscc in piping used in a boiling water reactor bwr. Sensitization is common in austentic stainless steels following welding or after prolonged exposure to service. Effects of marine environments on stress corrosion. The chloride concentration in desalted water of case a mgl. In support of the supercritical water reactor program, corrosion and stress corrosion cracking have been studied in pure supercritical water in ferriticmartenitic steels, austenitic stainless steels, nibase alloys, zrbase alloys, and tibase alloys. Conclusion a stress corrosion cracking constant load test method was used. Effect of plastic deformation induced by cold rolling or surface machining on the susceptibility to chlorideinduced stress corrosion cracking at ambient temperature of 304l austenitic stainless. Exposure of the austenitic stainless steel piping or equipment to moisture and air can lead to a potential for this type of cracking if the ss is sensitized. Chloride induced stress corrosion cracking of stainless.
Materials testing gives you an overview of important tests used in evaluating the corrosion behavior of metals and alloys, including zinc, lead, aluminum, steels, copper, nickel, stainless steels, cobaltbase alloys, titanium, zirconium and hafnium, tantalum and niobium alloys, metallic coatings on steel, nonmetallic coatings, metal matrix. In the chemical process industry, the most commonly used materials of construction are the carbon steels and 300 series austenitic stainless steels. In 2007, badak lng experienced this problem on its amine regenerator pressure vessel where the shell are insulated and made of austenitic stainless steel grade. Intergranular stress corrosion cracking of welded steel twi. Experience survey stress corrosion cracking of austenitic stainless steel. Chloride stress corrosion cracking in austenitic stainless steel. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. The promise of grain boundary engineering and surface modification in addressing corrosion and stress corrosion cracking performance is discussed. We use cookies to offer you a better experience, personalize content, tailor advertising, provide social media.
These operations optimize inservice properties such as resistance to pitting corrosion and stress corrosion cracking scc. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. The oxide originated on surface could act as a crack initiator and a crack propagation would progress along grain boundaries and particularly along tunnel of pores. Chloride is the dominant anion in ocean water, where its concentration is 1.
Thierry, lowtemperature stress corrosion cracking of stainless steels in the atmosphere in the presence of chloride deposits, corrosion 65, 105. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Nuregcr7170 assessment of stress corrosion cracking. Laboratory studies and operational experience indicate that austenitic stainless steel is. Abstractin pressurised water reactor primary water, there is generally growing concern that stress corrosion cracking scc may occur in occluded locations where residual oxygen and other impurities may be trapped.
For these critical components, the deployment of more scc resistant materials is desirable. The interaction of corrosion fatigue and stresscorrosion. Influence of high temperature on corrosion behavior of 304. Abstractstress corrosion cracking scc behaviours of z3cn2009m stainless steel in high temperature water containing cl. Pitting corrosion of stainless steels, on the other hand, occurs in solutions of all. The methodology of the drip procedure of the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to the insulation industry. Boiling water reactors bwrs experienced intergranular stress corrosion cracking igscc in austenitic stainless steel during this time.
Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl. Austenitic stainless steels are widely used in hydroprocessing units. But even in pure water, metal dissolution and hydrolysis can cause acidification in the crevice sedriks, 1996. Two different tests were conducted related to chloride stress corrosion cracking of 316 austenitic stainless steels in 3. In this study the influence of operating conditions such as chloride concentration, temperature on stress corrosion cracking of austenitic stainless steel will be investigated. Atmospheric stress corrosion crack growth rate analyses of. Avoiding stress corrosion cracking of carbon low alloy and austenitic stainless steels in chloride and caustic environments synopsis this maintenance best practice guide is concerned with the performance of carbon and low alloy steels, and austenitic stainless steels, in chloride and caustic containing fluids.
It appears that stress corrosion cracking in austenitic stainless steels in the. This form of corrosion is controlled by maintaining low chloride ion and oxygen content in the environment and use of low carbon steels. Chlorideinduced transgranular stress corrosion cracking. The influence of material factors on the intergranular stress corrosion cracking igscc susceptibility of austenitic stainless steels under hydrogenated hightemperature water were studied using the constant extension rate technique cert using specimens with a cold deformed hump. Chloride stress corrosion cracking of an austenitic. Stress corrosion cracking of austenitic stainless steel stress corrosion cracking is the failure of austenitic stainless steels caused by the combined action of a corrosive atmosphere and residual stress in the metal. Stainless steels are more resistant to general corrosion compared with carbon steel. Crevice conditions can enhance the corrosion, especially when combined with impurities. Stress corrosion cracking scc has been a degradation mechanism that has been a significant issue in the nuclear power industry for approximately 30 years. Avoiding stress corrosion cracking of carbon low alloy and. The results indicated that scc sensitivity was inconsistent with test temperature. As a general rule, the resistance to caustic solutions increases with. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. External stress corrosion cracking escc of austenitic.
Corrosion and stress corrosion cracking in supercritical water. A general definition of the phenomenon is that scc is the fracture of a material by the simultaneous action of a tensile stress and a corrosive environment. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. Corrosion resistance of austenitic and duplex stainless steels in. Chloride stress corrosion cracking in austenitic stainless. Considerable reactor experience has shown that a hightemperature water environment and a radiation field combine to produce irradiationassisted stress corrosion cracking iascc in core components of light water reactors. In austenitic stainless steel, the main forms of corrosion are pitting and stress corrosion cracking caused by chlorides. Intergranular stress corrosion cracking behavior of. Intergranular stress corrosion cracking was observed. When exposed to oxygen, whether in air or even in water, this layer will naturally form and will help to prevent corrosion of stainless steel beneath it. Schematic view of stress corrosion cracking scc and corrosion fatigue cracking. Each of these alloy families is subject to specific forms of insulationrelated corrosion. Cases of scc due to chlorides have been experienced at ambient.
At this minimum chromium content a stable cr oxidehydroxide a passive film forms on the surface of the steel. Stress corrosion cracking on an insulated austenitic. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic.
Alloy 20 carpenter 20 is an austenitic stainless steel possessing excellent resistance to hot sulfuric acid and many other aggressive environments which would readily attack type 316 stainless. Ss 316 austenitic stainless steel grade steelindo persada. Fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Sour service limits of dualcertified 316316l steel twi. Stress corrosion cracking scc of duplex stainless steel. Pdf assessment of stress corrosion cracking susceptibility for.
This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Ak steel nitronic 19d stainless steel is a lean duplex stainless steel with a mixed ferrite and austenite structure. Influence of high temperature on corrosion behavior of 304 stainless steel in chloride solutions aip advances 6, 115301 2016. Corrosion of this type has been extensively studied and affects almost all metal alloys, including the austenitic grades of stainless steel used in brewing. The effect of salt loading on chlorideinduced stress. Although the deterioration of austenitic stainless steels. Design features that trap water and may allow chloride concentration when plant is.
Effects of surface finishing on stress corrosion cracking. Austenitic stainless steels and nibase alloys have better oxidation resistance but are more susceptible to stress corrosion cracking. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in. Cracking is due to sulfur acids forming from sulfide scale, air and moisture acting on sensitized austenitic stainless steels. Standard austenitic steels are vulnerable to stress corrosion cracking.
Pdf the stress corrosion cracking of austenitic stainless steel. Stress corrosion cracking of austenitic stainless steel. A survey of the literature published up to date reveals that this technique was. They can be subject to polythionic acid stress corrosion cracking during shut down. This alloy exhibits superior resistance to stress corrosion cracking in boiling 2040% sulfuric acid. Nace sp0170 protection of austenitic stainless steels. Scc behaviours of austenitic stainless steel z3cn2009m in. Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment this standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from pta scc that can occur during a shutdown of refinery equipment. The objective of the work described in this paper was to further the understanding of atmospheric crack growth rate of stainless steel in a chloriderich environment. The effectiveness of this protective oxide layer can become compromised when the original oxide surface layer becomes damaged or scratched.
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